This separation marks the third for the latin star, who was previously married to Miss Universe 1993 Dayanara Torres and subsequently Jennifer Lopez. Anthony shares two sons, Cristian and Ryan, with Torres and twins Emme and Max with Lopez.
The news comes on the heels of his surprise liplock with Lopez, who broke up with boyfriend Casper Smart in August, on the Latin Grammy Award stage Thursday night.
After performing their new duet, "Olvídame y Pega la Vuelta," the pop star presented her former beau with the Person of the Year Award and embraced him in a kiss, sending the crowd into a roar of applause.
De Lima was noticeably missing from the award ceremony and Anthony was not wearing his wedding ring.
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